Analytical procedures for voltammetric analysis

These analytical procedures, if not differently specified, are to be applied to limpid solutions not containing oxidising or reducing agents, suspended solids, organic substances and colloids. Samples are meant to be prepared in order to fulfil these conditions, leading to a final solution of pH in the range 1 – 10, to avoid any damage to the equipment. Prepare samples, standard solutions for additions and supporting electrolytes using ultra- pure bidistilled water and clean chemicals (reagents for trace metals analysis). Always perform a blank analysis when environmental pollutants are investigated, like lead, zinc, copper, iron and chlorides.

Elements or Compound Description PDF .met
Aluminium Method: Calcon in 0.1 M acetate buffer, pH 4.7. Differential Pulse Voltammetry (DPV/a) IT EN AMEL
Antimony Differential Pulse Stripping Voltammetry (DPS/a)
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Arsenic (total) Differential Pulse Stripping Voltammetry (DPS/a). Electrode: Gold film on glassy carbon electrode
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Ascorbic acid in fruit juice Differential Pulse Voltammetry (DPV/a)
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Bismuth Differential Pulse Stripping Voltammetry (DPS/a)
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Boric acid in nickel plating bath Differential Pulse Voltammetry (DPV/a)
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Cadmium Differential Pulse Stripping Voltammetry (DPS/a)
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Chlorides Differential Pulse Voltammetry (DPV/a)
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Chromium (VI and total) Method: DTPA in 0.2 M acetate buffer, pH 6.2. Differential Pulse Adsorptive Stripping Voltammetry (DPS/a) IT EN AMEL
Cobalt Method: Dimetilglioxime in 0.1 M tartrate buffer, pH 9. Differential Pulse Voltammetry (DPV/a)
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Copper Differential Pulse Stripping Voltammetry (DPS/a) IT EN AMEL
Cyanides Differential Pulse Voltammetry (DPV/a)
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Formaldehyde Differential Pulse Voltammetry (DPV/a)
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Iron Method: Triethanolamine – Sodium hydroxide buffer. Differential Pulse Voltammetry (DPV/a).
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Lead Differential Pulse Stripping Voltammetry (DPS/a) IT EN AMEL
Manganese Differential Pulse Stripping Voltammetry (DPS/a) . Electrode: Glassy carbon IT EN AMEL
Mercury Square Wave Stripping Voltametry (SQS). Electrode: rotating gold electrode (2 mm diameter)
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Molybdenum Method: Mandelic acid in H2SO4, pH 3-3.5 Differential Pulse Voltammetry (DPV/a) IT EN AMEL
Nickel Method: Dimetilglioxime in 0.1 M tartrate buffer, pH 9. Differential Pulse Voltammetry (DPV/a) IT EN AMEL
Nitrites Differential Pulse Voltammetry (DPV/a)
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Palladium Method: Dimetilglioxime in 0.1 M tartrate buffer, pH 5.15. Differential Pulse Stripping Voltammetry (DPS/a)
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Platinum Differential Pulse Voltammetry (DPV/a) IT EN AMEL
Saccharin in nickel plating bath Differential Pulse Voltammetry (DPV/a)
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Selenium Differential Pulse Stripping Voltammetry (DPS/a)
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Silver Differential Pulse Stripping Voltammetry (DPS/a). Electrode: Glassy carbon
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Sulphides Differential Pulse Voltammetry (DPV/a)
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Sulphur dioxide (sulphites) Differential Pulse Voltammetry (DPV/a) IT EN AMEL
Sulphur in gasoline and petroleum Differential Pulse Voltammetry (DPV/a)
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Thallium Differential Pulse Stripping Voltammetry (DPS/a)
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Thiourea in nickel and copper plating bath Differential Pulse Voltammetry (DPV/a)
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Tin Method: tropolone in oxalic – hydrochloric acid. Differential Pulse Voltammetry (DPV/a)
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Total Aldehydes Method: Hydrazine in 0.1 M citrate buffer, pH 6.5. Differential Pulse Voltammetry (DPV/a)
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Vanadium Differential Pulse Stripping Voltammetry (DPS/a)
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Zinc (high levels) Differential Pulse Voltammetry (DPV/a)
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Zinc (low levels) Differential Pulse Stripping Voltammetry (DPS/a) IT EN AMEL