Analytical procedures for voltammetric analysis
These analytical procedures, if not differently specified, are to be applied to limpid solutions not containing oxidising or reducing agents, suspended solids, organic substances and colloids. Samples are meant to be prepared in order to fulfil these conditions, leading to a final solution of pH in the range 1 – 10, to avoid any damage to the equipment. Prepare samples, standard solutions for additions and supporting electrolytes using ultra- pure bidistilled water and clean chemicals (reagents for trace metals analysis). Always perform a blank analysis when environmental pollutants are investigated, like lead, zinc, copper, iron and chlorides.
Elements or Compound | Description | .met | ||
---|---|---|---|---|
Aluminium | Method: Calcon in 0.1 M acetate buffer, pH 4.7. Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Antimony | Differential Pulse Stripping Voltammetry (DPS/a) | IT | EN | |
Arsenic (total) | Differential Pulse Stripping Voltammetry (DPS/a). Electrode: Gold film on glassy carbon electrode | IT | EN | |
Ascorbic acid in fruit juice | Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Bismuth | Differential Pulse Stripping Voltammetry (DPS/a) | IT | EN | |
Boric acid in nickel plating bath | Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Cadmium | Differential Pulse Stripping Voltammetry (DPS/a) | IT | EN | |
Chlorides | Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Chromium (VI and total) | Method: DTPA in 0.2 M acetate buffer, pH 6.2. Differential Pulse Adsorptive Stripping Voltammetry (DPS/a) | IT | EN | |
Cobalt | Method: Dimetilglioxime in 0.1 M tartrate buffer, pH 9. Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Copper | Differential Pulse Stripping Voltammetry (DPS/a) | IT | EN | |
Cyanides | Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Formaldehyde | Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Iron | Method: Triethanolamine – Sodium hydroxide buffer. Differential Pulse Voltammetry (DPV/a). | IT | EN | |
Lead | Differential Pulse Stripping Voltammetry (DPS/a) | IT | EN | |
Manganese | Differential Pulse Stripping Voltammetry (DPS/a) . Electrode: Glassy carbon | IT | EN | |
Mercury | Square Wave Stripping Voltametry (SQS). Electrode: rotating gold electrode (2 mm diameter) | IT | EN | |
Molybdenum | Method: Mandelic acid in H2SO4, pH 3-3.5 Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Nickel | Method: Dimetilglioxime in 0.1 M tartrate buffer, pH 9. Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Nitrites | Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Palladium | Method: Dimetilglioxime in 0.1 M tartrate buffer, pH 5.15. Differential Pulse Stripping Voltammetry (DPS/a) | IT | EN | |
Platinum | Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Saccharin in nickel plating bath | Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Selenium | Differential Pulse Stripping Voltammetry (DPS/a) | IT | EN | |
Silver | Differential Pulse Stripping Voltammetry (DPS/a). Electrode: Glassy carbon | IT | EN | |
Sulphides | Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Sulphur dioxide (sulphites) | Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Sulphur in gasoline and petroleum | Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Thallium | Differential Pulse Stripping Voltammetry (DPS/a) | IT | EN | |
Thiourea in nickel and copper plating bath | Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Tin | Method: tropolone in oxalic – hydrochloric acid. Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Total Aldehydes | Method: Hydrazine in 0.1 M citrate buffer, pH 6.5. Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Vanadium | Differential Pulse Stripping Voltammetry (DPS/a) | IT | EN | |
Zinc (high levels) | Differential Pulse Voltammetry (DPV/a) | IT | EN | |
Zinc (low levels) | Differential Pulse Stripping Voltammetry (DPS/a) | IT | EN |